loading
附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉 布斯函数、标准摩尔熵和摩尔热容(100kPa)>
(1)单质和无机物 物质 Ag(s) Ag2CO3(s) Ag2O(s) Al(s) Al(g) Al2O3-α Al2(SO4)3(s) Br2(g) Br2(g) Br2(l) C(g) C(金刚石) C(石墨) CO(g) CO2(g) Ca(s) CaC2(s) CaCO3(方解石) CaCl2(s) CaO(s) Ca(OH)2(s) CaSO4(硬石膏) Cl-(aq) Cl2(g) Cu(s) CuO(s) Cu2O-α F2(g) -167.456 0 0 -155.2 -166.69 0 -131.168 0 0 -127.1 -146.33 0 55.10 222.948 33.32 43.51 100.8 203.5 -795.0 -635.6 -986.5 -1432.68 -750.2 -604.2 -896.89 -1320.24 113.8 39.7 76.1 106.7 72.63 48.53 84.5 97.65 yy -1Smy(298.15K) J·Kmol-1-1-1ΔfHm(298.15K) ΔfGm(298.15K) kJ·mol0 -506.14 -30.56 0 313.80 -1669.8 -3434.98 111.884 30.71 0 718.384 1.896 0 -110.525 -393.511 0 -62.8 -1206.87 Cp,my(298.15K) J·K·mol25.48 -1-1 kJ·mol0 42.712 167.36 121.71 28.315 164.553 0.986 239.3 175.021 245.455 152.3 158.101 2.439 5.694 198.016 213.76 41.63 70.2 92.8 -437.09 -10.82 0 273.2 -2213.16 -3728.53 82.396 3.109 0 672.942 2.866 0 -137.285 -394.38 0 -67.8 -1128.70 65.57 24.35 79.0 259.4 35.99 35.6 6.07 8.66 29.142 37.120 26.27 62.34 81.83 33.9 24.47 44.4 69.8 31.46
Fe-α FeCO3(s) FeO(s) Fe2O3(s) Fe3O4(s) H(g) H2(g) D2(g) HBr(g) HBr(aq) HCl(g) HCl(aq) H2CO3(aq) Hl(g) H2O(g) H2O(l) H2O(s) H2O2(l) H2S(g) H2SO4(l) H2SO4(aq) HSO4(aq) l2(g) I2(g) N2(g) NH3(g) NO(g) NO2(g) N2O(g) N2O4(g) N2O5(g) O(g) O2(g) O3(g) OH-(aq) 0 -747.68 -266.52 -822.1 -117.1 217.94 0 0 -36.24 -120.92 -92.311 -167.44 -698.7 -25.94 -241.825 -285.838 -291.850 -187.61 -20.146 -811.35 -811.32 -885.75 0 62.242 0 -46.19 89.860 33.85 81.55 9.660 2.51 247.521 0 142.3 -229.940 0 -673.84 -244.3 -741.0 -1014.1 203.122 0 0 -53.22 -102.80 -95.265 -131.17 -623.37 -1.32 -228.577 -237.142 (-234.03） -118.04 -33.040 (-866.4） 27.15 92.8 54.0 90.0 146.4 114.724 130.695 144.884 198.60 80.71 186.786 55.10 191.2 206.42 188.823 69.940 (39.4） 102.26 205.75 156.85 25.23 82.13 51.1 104.6 143.42 20.80 28.83 29.20 29.12 29.12 29.12 33.571 75.296 82.29 33.97 137.57 -752.99 0 19.34 0 -16.603 90.37 51.86 103.62 98.39 110.5 230.095 0 163.45 -157.297 126.86 116.7 260.60 191.598 192.61 210.309 240.57 220.10 304.42 342.4 161.063 205.138 237.7 -10.539 55.97 36.87 29.12 35.65 29.861 37.90 38.70 79.0 108.0 21.93 29.37 38.15
S(单斜) S(斜方) (g) S(g) SO2(g) SO3(g) SO4 (aq) 2-0.29 0 124.94 222.80 -296.90 -395.18 -907.51 0.096 0 76.08 182.27 -300.37 -370.40 -741.90 32.55 31.9 227.76 167.825 248.64 256.34 17.2 23.64 22.60 32.55 39.79 50.70
(2)有机化合物 物质 ΔfHm(298.15K) y ΔfGm(298.15K) Sm(298.15K) yyCp,my(298.15K) J·K·mol35.715 43.928 43.56 52.650 63.89 73.51 79.54 85.65 78.91 87.82 89.12 97.45 96.82 81.67 135.77 106.27 143.09 194.93 103.76 157.11 133.26 187.9 127.57 183.3 126.86 183.7 -1-1 CH4(g), 甲烷 C2H2(g), 乙炔 C2H4(g), 乙烯 C2H6(g), 乙烷 C3H6(g), 丙烯 C3H6(g), 丙烷 C4H6(g), 1,3-丁二烯 C4H8(g), 1-丁烯 C4H8(g), 顺-2-丁烯 C4H8(g), 反-2-丁烯 C4H8(g), 2-甲基两烯 C4H10(g), 正丁烷 C4H10(g), 异丁烷 C6H6(g), 苯 C6H6(l), 苯 C6H12(g), 环己烷 C6H14(g), 正己烷 C6H14(l), 正己烷 C6H5CH3(g),甲苯 C6H5CH3(l),甲苯 C6H4(CH2）(g)C6H4邻二甲苯 间二甲苯 对二甲苯 C6H4（CH3）2(l), 邻二甲苯 （CH3）2(g),C6H（CH3）2（l), 间二甲苯 C6H4（CH3）2(g),C6H4（CH3）2(l), 对二甲苯 烃 类 -74.847 226.748 52.283 -84.667 20.414 -103.847 110.16 -0.13 -6.99 -11.17 -16.90 -126.15 -134.52 82.927 49.028 -123.14 -167.19 -198.82 49.999 11.995 18.995 -24.439 17.238 -25.418 17.949 -24.426 kJ·mol-1kJ·mol-1 J·Kmol-1-1 50.827 209.200 68.157 -32.821 62.783 -23.391 150.74 71.60 65.96 63.07 58.17 -17.02 -20.79 129.723 124.597 31.92 -0.09 -4.08 122.388 114.299 122.207 110.495 118.977 107.817 121.266 110.244 186.30 200.928 219.56 229.60 267.05 270.02 278.85 305.71 300.94 296.59 293.70 310.23 294.75 269.31 172.35 298.51 388.85 295.89 319.86 219.58 352.86 246.48 357.80 252.17 352.53 247.36